One-Electron Oxidized Nickel(II)−(Disalicylidene)diamine Complex:  Temperature-Dependent Tautomerism between Ni(III)−Phenolate and Ni(II)−Phenoxyl Radical States

One-Electron Oxidized Nickel(II)−(Disalicylidene)diamine Complex:  Temperature-Dependent Tautomerism between Ni(III)−Phenolate and Ni(II)−Phenoxyl Radical States

The one-electron oxidized species of a Ni(II)−phenolate complex has been shown to be in the Ni(II)−phenoxyl radical state at room temperature and the Ni(III)−phenolate state at

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Veröffentlicht in:Journal of the American Chemical Society 2003-09, Vol.125 (35), p.10512-10513
Hauptverfasser: Shimazaki, Yuichi, Tani, Fumito, Fukui, Kôichi, Naruta, Yoshinori, Yamauchi, Osamu
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
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Beschreibung
Zusammenfassung:The one-electron oxidized species of a Ni(II)−phenolate complex has been shown to be in the Ni(II)−phenoxyl radical state at room temperature and the Ni(III)−phenolate state at
ISSN:0002-7863
1520-5126
DOI:10.1021/ja035806o