Host-Guest Antenna Materials

The focus of this review is on host–guest composites with photonic antenna properties. The material generally consists of cylindrical zeolite L crystals the channels of which are filled with dye molecules. The synthesis is based on the fact that molecules can diffuse into individual channels. This means that, under the appropriate conditions, they can also leave the zeolite by the same way. In some cases, however, it is desirable to block their way out by adding a closure molecule. Functionalization of the closure molecules allows tuning of, for example, wettability, refractive index, and chemical reactivity. The supramolecular organization of the dyes inside the channels is a first stage of organization. It allows light harvesting within a certain volume of a dye‐loaded nanocrystalline zeolite and radiationless transport to both ends of the cylinder or from the ends to the center. The second stage of organization is the coupling to an external acceptor or donor stopcock fluorophore at the ends of the channels, which can trap or inject electronic excitation energy. The third stage of organization is the coupling to an external device through a stopcock molecule. The wide‐ranging tunability of these highly organized materials offers fascinating new possibilities for exploring excitation‐energy‐transfer phenomena, and challenges for developing new photonic devices. Dyeing Zeolites: Dye‐zeolite antenna systems transporting excitation energy over large distances are discussed on the basis of three stages of organization: the supramolecular organization of dye molecules inside the zeolite channels, the organization of stopcock molecules plugging the channel entrances, and the coupling of stopcock‐modified antenna systems to an external device (see picture; EnT=energy transfer).