Enhanced pi ... pi interactions in alpha,beta-unsaturated carbonyls

Enhanced pi ... pi interactions in alpha,beta-unsaturated carbonyls

High level ab initio calculations on complexes of benzene with acrolein and ethene reveal that pi ... pi interactions to electron deficient acrolein are remarkably similar to those found in the benzene dimer.

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Veröffentlicht in:Organic & biomolecular chemistry 2003-02, Vol.1 (3), p.457-459
Hauptverfasser: Harris, Lisa D, Platts, James A, Tomkinson, Nicholas C
Format: Artikel
Sprache:eng
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Zusammenfassung:High level ab initio calculations on complexes of benzene with acrolein and ethene reveal that pi ... pi interactions to electron deficient acrolein are remarkably similar to those found in the benzene dimer.
ISSN:1477-0520
DOI:10.1039/b210497k