A Well-Defined Complex for Palladium-Catalyzed Aerobic Oxidation of Alcohols: Design, Synthesis, and Mechanistic Considerations

A Well-Defined Complex for Palladium-Catalyzed Aerobic Oxidation of Alcohols: Design, Synthesis, and Mechanistic Considerations

A breath of fresh air: A variety of alcohols are oxidized using 0.5–0.1 mol % of the catalyst, and in some cases the oxidation can simply be carried out open to the air (see scheme). Mechanistic insight into the mechanism is provided by a crystal structure that shows remarkable hydrogen bonds betwee...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2003-08, Vol.42 (32), p.3810-3813
Hauptverfasser: Jensen, David R., Schultz, Mitchell J., Mueller, Jaime A., Sigman, Matthew S.
Format: Artikel
Sprache:eng
Schlagworte:
Aerobiosis
alcohols
Alcohols - chemistry
Allyl Compounds - chemical synthesis
Allyl Compounds - chemistry
Benzyl Alcohols - chemical synthesis
Benzyl Alcohols - chemistry
Catalysis
Crystallography, X-Ray
Magnetic Resonance Spectroscopy
oxidation
Oxidation-Reduction
oxygen
Oxygen - chemistry
palladium
Palladium - chemistry
reaction mechanisms
Thermodynamics
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A breath of fresh air: A variety of alcohols are oxidized using 0.5–0.1 mol % of the catalyst, and in some cases the oxidation can simply be carried out open to the air (see scheme). Mechanistic insight into the mechanism is provided by a crystal structure that shows remarkable hydrogen bonds between the coordinated water and acetate ligands and an unprecedented large kinetic isotope effect.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351997