(Tetrahydrofuran)potassium mer-trans-tris(carbazolyl)dichloro-(tetrahydrofuran)zirconate

In the title compound, [K(C(4)H(8)O)][ZrCl(2)(C(12)H(8)N)(3)(C(4)H(8)O)], the Zr atom is pseudo-octahedral, with two Cl ligands in trans positions. There is extensive interaction between the potassium cation and two of the aromatic carbazolyl ligands in eta(6) [C.K = 3.167 (3)-3.331 (3) A] and eta(2...

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Veröffentlicht in:	Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-07, Vol.59 (Pt 7), p.m275-m276
Hauptverfasser:	NYGREN, Cara L, BRAGG, M. E. T, TURNER, John F. C
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic compounds Metal complexes Physics Structure of solids and liquids crystallography Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:	In the title compound, [K(C(4)H(8)O)][ZrCl(2)(C(12)H(8)N)(3)(C(4)H(8)O)], the Zr atom is pseudo-octahedral, with two Cl ligands in trans positions. There is extensive interaction between the potassium cation and two of the aromatic carbazolyl ligands in eta(6) [C.K = 3.167 (3)-3.331 (3) A] and eta(2) [C.K = 3.147 (3)-3.268 (2) A] fashions.
ISSN:	0108-2701 1600-5759
DOI:	10.1107/S0108270103010321