Green oxidation with aqueous hydrogen peroxide

Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in an economically, technically, and environmentally s...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-01 (16), p.1977-1986
Hauptverfasser: Noyori, Ryoji, Aoki, Masao, Sato, Kazuhiko
Format: Artikel
Sprache:eng
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Zusammenfassung:Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in an economically, technically, and environmentally satisfying manner.
ISSN:1359-7345
1364-548X
DOI:10.1039/b303160h