A New Cationic, Chiral Catalyst for Highly Enantioselective Diels−Alder Reactions

The Diels−Alder reaction of cyclopentadiene and 2-methacrolein is catalyzed by a chiral Lewis acid to form the exo adduct in 96% yield and 96% ee.

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Veröffentlicht in:	Organic letters 2003-07, Vol.5 (14), p.2465-2467
Hauptverfasser:	Sprott, Kevin T, Corey, E. J
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Cations - chemistry Stereoisomerism
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description	The Diels−Alder reaction of cyclopentadiene and 2-methacrolein is catalyzed by a chiral Lewis acid to form the exo adduct in 96% yield and 96% ee.
doi_str_mv	10.1021/ol034706k
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subjects	Catalysis Cations - chemistry Stereoisomerism
title	A New Cationic, Chiral Catalyst for Highly Enantioselective Diels−Alder Reactions
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