A New Cationic, Chiral Catalyst for Highly Enantioselective Diels−Alder Reactions

A New Cationic, Chiral Catalyst for Highly Enantioselective Diels−Alder Reactions

The Diels−Alder reaction of cyclopentadiene and 2-methacrolein is catalyzed by a chiral Lewis acid to form the exo adduct in 96% yield and 96% ee.

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Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2003-07, Vol.5 (14), p.2465-2467
Hauptverfasser: Sprott, Kevin T, Corey, E. J
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Cations - chemistry
Stereoisomerism
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Beschreibung
Zusammenfassung:The Diels−Alder reaction of cyclopentadiene and 2-methacrolein is catalyzed by a chiral Lewis acid to form the exo adduct in 96% yield and 96% ee.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol034706k