The use of a germene for the synthesis of esters of alpha-germyl-substituted alpha-amino acid and alpha-aminophosphonic acid

The first alpha-germyl-substituted alpha-amino ester and alpha-germyl-substituted alpha-aminophosphonic ester have been synthesized by a one-pot reaction between the germene Mes2Ge=CR2 (CR2 = fluorenylidene) and the iminoester or iminophosphonate Ph(H)C=NCH2-Y (Y = COOMe, P(O)(OEt)2).

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2003-01 (14), p.1662-1663
Hauptverfasser:	El Kettani, S Ech-Cherif, Escudié, J, Couret, C, Ranaivonjatovo, H, Lazraq, M, Soufiaoui, M, Gornitzka, H, Nemes, G Cretiu
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino Acids - chemical synthesis Esters Germanium - chemistry Organophosphonates - chemical synthesis
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The first alpha-germyl-substituted alpha-amino ester and alpha-germyl-substituted alpha-aminophosphonic ester have been synthesized by a one-pot reaction between the germene Mes2Ge=CR2 (CR2 = fluorenylidene) and the iminoester or iminophosphonate Ph(H)C=NCH2-Y (Y = COOMe, P(O)(OEt)2).
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b303661h