A Near-Infrared Electrochromic Window Based on an Sb-Doped SnO2 Electrode Modified with a Ru-Dioxolene Complex

A Near-Infrared Electrochromic Window Based on an Sb-Doped SnO2 Electrode Modified with a Ru-Dioxolene Complex

A window of opportunity: The ligand‐centred redox activity of complex 1 (depicted) is exploited to make an electrochromic window, which demonstrates rapid and reversible changes in optical transmission at 940 nm. The window is made by adsorbing 1 onto a nanocrystalline Sb‐doped SnO2 film attached to...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-07, Vol.42 (26), p.3011-3014
Hauptverfasser: García-Cañadas, Jorge, Meacham, Andrew P., Peter, Laurence M., Ward, Michael D.
Format: Artikel
Sprache:eng
Schlagworte:
cyclic voltammetry
electrochemistry
electrochromism
near infrared
ruthenium
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Zusammenfassung:A window of opportunity: The ligand‐centred redox activity of complex 1 (depicted) is exploited to make an electrochromic window, which demonstrates rapid and reversible changes in optical transmission at 940 nm. The window is made by adsorbing 1 onto a nanocrystalline Sb‐doped SnO2 film attached to a transparent conducting substrate and cycling the applied potential through the catecholate/semiquinone redox couple.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351338