Structural and Magnetic Properties of a Novel Ferrocenyl−Diiodine Charge Transfer Complex

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented “double” charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

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Bibliographische Detailangaben
Veröffentlicht in:	Inorganic chemistry 2003-06, Vol.42 (13), p.3975-3977
Hauptverfasser:	Allen, David W, Berridge, Rory, Bricklebank, Neil, Forder, Susan D, Palacio, Fernando, Coles, Simon J, Hursthouse, Michael B, Skabara, Peter J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented “double” charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.
ISSN:	0020-1669 1520-510X
DOI:	10.1021/ic034092f