Solid-State Supramolecular Organization of Supermolecules into a Truly Molecular Zeolite

Solid-State Supramolecular Organization of Supermolecules into a Truly Molecular Zeolite

Letting out the guests: The hexagonal closest packing of discrete triangular‐tube‐shaped organometallic supermolecules of eclipsed‐[{Ru2(CO)4(PPh3)2}(μ‐4,4′‐O2CC6H4C6H4CO2)]3 in the solid state (see picture) permits the production of a microporous material that is not only thermally stable up to 181...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-07, Vol.42 (26), p.2999-3001
Hauptverfasser: Shiu, Kom-Bei, Lee, Hong-Chan, Lee, Gene-Hsiang, Ko, Bao-Tsan, Wang, Yu, Lin, Chu-Chieh
Format: Artikel
Sprache:eng
Schlagworte:
microporous materials
noncovalent interactions
self-assembly
supramolecular chemistry
zeolite analogues
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Zusammenfassung:Letting out the guests: The hexagonal closest packing of discrete triangular‐tube‐shaped organometallic supermolecules of eclipsed‐[{Ru2(CO)4(PPh3)2}(μ‐4,4′‐O2CC6H4C6H4CO2)]3 in the solid state (see picture) permits the production of a microporous material that is not only thermally stable up to 181 °C, but also allows diffusion at room temperature of molecular guests without the framework collapsing.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351149