A self-assembling polymer-bound rotaxane under thermodynamic control

A self-assembling polymer-bound rotaxane under thermodynamic control

The thermodynamically controlled self-assembly of a neutral donor-acceptor rotaxane, stoppered via porphyrin coordination and bound to polystyrene beads is described, and the dynamic equilibrium between solid and solution phases has been examined by HR MAS nmr spectroscopy.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-01 (12), p.1396-1397
Hauptverfasser: Johnstone, Ken D, Bampos, Nick, Sanders, Jeremy K M, Gunter, Maxwell J
Format: Artikel
Sprache:eng
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Zusammenfassung:The thermodynamically controlled self-assembly of a neutral donor-acceptor rotaxane, stoppered via porphyrin coordination and bound to polystyrene beads is described, and the dynamic equilibrium between solid and solution phases has been examined by HR MAS nmr spectroscopy.
ISSN:1359-7345
1364-548X
DOI:10.1039/b302071a