Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid-base pairs

A facile synthetic approach is reported for the synthesis of dissymmetric 1,2-ferrocenediyl Lewis acids and mixed acid-base pairs including the first example of a 1-phosphino-2-borylferrocene; the use of non-racemic electrophiles allows for the isolation of single diastereomer products.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2009-01 (47), p.7288-7290
Hauptverfasser:	Morgan, Ian R, Di Paolo, Angela, Vidovic, Dragoslav, Fallis, Ian A, Aldridge, Simon
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A facile synthetic approach is reported for the synthesis of dissymmetric 1,2-ferrocenediyl Lewis acids and mixed acid-base pairs including the first example of a 1-phosphino-2-borylferrocene; the use of non-racemic electrophiles allows for the isolation of single diastereomer products.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b917304h