Fluorescence turn-on sensors for HSO4

A coumarin-based derivative (1), a highly selective and sensitive turn-on fluorogenic probe for the detection of HSO4- ions in aqueous solution, has been designed and synthesized. Various spectroscopic and DFT calculations revealed that H-bonding between the phenolic -OH and imine nitrogen of 1 play...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (46), p.7128-7130
Hauptverfasser: Kim, Hyun Jung, Bhuniya, Sankarprasad, Mahajan, Rakesh Kumar, Puri, Rajiv, Liu, Hongguang, Ko, Kyoung Chul, Lee, Jin Yong, Kim, Jong Seung
Format: Artikel
Sprache:eng
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Zusammenfassung:A coumarin-based derivative (1), a highly selective and sensitive turn-on fluorogenic probe for the detection of HSO4- ions in aqueous solution, has been designed and synthesized. Various spectroscopic and DFT calculations revealed that H-bonding between the phenolic -OH and imine nitrogen of 1 played a crucial role in its high selectivity for HSO4-.
ISSN:1359-7345
1364-548X
DOI:10.1039/b918324h