Silver-catalysed protodecarboxylation of carboxylic acids

A silver-based catalyst system has been discovered that effectively promotes the protodecarboxylation of various carboxylic acids at temperatures of 80-120 degrees C--more than 50 degrees C below those of the best known copper catalysts.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2009-01 (46), p.7173-7175
Hauptverfasser:	Goossen, Lukas J, Linder, Christophe, Rodríguez, Nuria, Lange, Paul P, Fromm, Andreas
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic Acids - chemistry Carboxylic Acids - radiation effects Catalysis - radiation effects Decarboxylation - drug effects Decarboxylation - radiation effects Photochemical Processes Silver - chemistry Temperature
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A silver-based catalyst system has been discovered that effectively promotes the protodecarboxylation of various carboxylic acids at temperatures of 80-120 degrees C--more than 50 degrees C below those of the best known copper catalysts.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b912509d