Synthesis of Tin Dioxide Octahedral Nanoparticles with Exposed High-Energy {221} Facets and Enhanced Gas-Sensing Properties
Selective exposure of high‐energy {221} facets with many surface dangling bonds, (111) terraces, and (110) steps (bottom picture) at the surface of octahedral SnO2 nanoparticles (top) through a simple hydrothermal synthesis route gives them enhanced gas‐sensing performance over particles with other...
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Veröffentlicht in: | Angewandte Chemie (International ed.) 2009-11, Vol.48 (48), p.9180-9183 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Selective exposure of high‐energy {221} facets with many surface dangling bonds, (111) terraces, and (110) steps (bottom picture) at the surface of octahedral SnO2 nanoparticles (top) through a simple hydrothermal synthesis route gives them enhanced gas‐sensing performance over particles with other shapes, whereby the sensing activity is proportional to the fraction of {221} facets among the exposed surfaces. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200903926 |