One-Pot Synthesis of Symmetric and Unsymmetric 1,1-Bis-indolylmethanes via Tandem Iron-Catalyzed C−H Bond Oxidation and C−O Bond Cleavage

One-Pot Synthesis of Symmetric and Unsymmetric 1,1-Bis-indolylmethanes via Tandem Iron-Catalyzed C−H Bond Oxidation and C−O Bond Cleavage

The reactions of indoles with ethers give a variety of symmetric and unsymmetric 1,1-bis-indolylmethane derivatives via iron-catalyzed C−H bond oxidation and C−O bond cleavage.

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Veröffentlicht in:Journal of organic chemistry 2009-11, Vol.74 (22), p.8848-8851
Hauptverfasser: Guo, Xingwei, Pan, Shiguang, Liu, Jinhua, Li, Zhiping
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Indoles - chemical synthesis
Indoles - chemistry
Iron - chemistry
Molecular Structure
Organic chemistry
Oxidation-Reduction
Preparations and properties
Stereoisomerism
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Beschreibung
Zusammenfassung:The reactions of indoles with ethers give a variety of symmetric and unsymmetric 1,1-bis-indolylmethane derivatives via iron-catalyzed C−H bond oxidation and C−O bond cleavage.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo902093p