Systematic Metal Variation and Solvent and Hydrogen-Gas Storage in Supramolecular Nanoballs

Systematic Metal Variation and Solvent and Hydrogen-Gas Storage in Supramolecular Nanoballs

Play ball! A family of discrete metallo‐supramolecular nanoballs (see picture) containing different divalent metals is produced by self‐assembly. These species have porous structures, similar to metal–organic frameworks. Stepwise desolvation results in bare metal sites which can be functionalized wi...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-11, Vol.48 (47), p.8919-8922
Hauptverfasser: Duriska, Martin B, Neville, Suzanne M, Lu, Jinzhen, Iremonger, Simon S, Boas, John F, Kepert, Cameron J, Batten, Stuart R
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Sprache:eng
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hydrogen storage
microporous materials
nanostructures
solvent storage
supramolecular chemistry
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container_end_page 8922
container_issue 47
container_start_page 8919
container_title Angewandte Chemie (International ed.)
container_volume 48
creator Duriska, Martin B
Neville, Suzanne M
Lu, Jinzhen
Iremonger, Simon S
Boas, John F
Kepert, Cameron J
Batten, Stuart R
description Play ball! A family of discrete metallo‐supramolecular nanoballs (see picture) containing different divalent metals is produced by self‐assembly. These species have porous structures, similar to metal–organic frameworks. Stepwise desolvation results in bare metal sites which can be functionalized with organic molecules; the interball cavities show high affinity for hydrogen gas.
doi_str_mv 10.1002/anie.200903863
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subjects hydrogen storage
microporous materials
nanostructures
solvent storage
supramolecular chemistry
title Systematic Metal Variation and Solvent and Hydrogen-Gas Storage in Supramolecular Nanoballs
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