Systematic Metal Variation and Solvent and Hydrogen-Gas Storage in Supramolecular Nanoballs

Systematic Metal Variation and Solvent and Hydrogen-Gas Storage in Supramolecular Nanoballs

Play ball! A family of discrete metallo‐supramolecular nanoballs (see picture) containing different divalent metals is produced by self‐assembly. These species have porous structures, similar to metal–organic frameworks. Stepwise desolvation results in bare metal sites which can be functionalized wi...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-11, Vol.48 (47), p.8919-8922
Hauptverfasser: Duriska, Martin B, Neville, Suzanne M, Lu, Jinzhen, Iremonger, Simon S, Boas, John F, Kepert, Cameron J, Batten, Stuart R
Format: Artikel
Sprache:eng
Schlagworte:
hydrogen storage
microporous materials
nanostructures
solvent storage
supramolecular chemistry
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Beschreibung
Zusammenfassung:Play ball! A family of discrete metallo‐supramolecular nanoballs (see picture) containing different divalent metals is produced by self‐assembly. These species have porous structures, similar to metal–organic frameworks. Stepwise desolvation results in bare metal sites which can be functionalized with organic molecules; the interball cavities show high affinity for hydrogen gas.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200903863