Cobalt Antiferromagnetic Ring and Grid Single-Molecule Magnet

Grid magnet: A Co8 ring and a Co9 grid complex are synthesized using a multidentate polypyridine‐type ligand and are shown to exhibit all antiferromagnetic interactions between metal centers, with the grid complex displaying SMM properties as a result of alternating high spin/low spin metal centers...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry, an Asian journal an Asian journal, 2009-11, Vol.4 (11), p.1660-1663
Hauptverfasser: Shiga, Takuya, Matsumoto, Takuto, Noguchi, Mao, Onuki, Tatsuya, Hoshino, Norihisa, Newton, Graham N., Nakano, Motohiro, Oshio, Hiroki
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Grid magnet: A Co8 ring and a Co9 grid complex are synthesized using a multidentate polypyridine‐type ligand and are shown to exhibit all antiferromagnetic interactions between metal centers, with the grid complex displaying SMM properties as a result of alternating high spin/low spin metal centers in the outer 8‐membered ring.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.200900216