Microwave Chemistry in Silicon Carbide Reaction Vials: Separating Thermal from Nonthermal Effects

Microwave Chemistry in Silicon Carbide Reaction Vials: Separating Thermal from Nonthermal Effects

Running oil‐bath chemistry in a microwave! Using reaction vials made out of strongly microwave‐absorbing silicon carbide (SiC) in a microwave reactor simulates experiments conducted in an autoclave with conductive heating because of the efficient shielding of the electromagnetic field by the SiC via...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-10, Vol.48 (44), p.8321-8324
Hauptverfasser: Obermayer, David, Gutmann, Bernhard, Kappe, C. Oliver
Format: Artikel
Sprache:eng
Schlagworte:
Carbon Compounds, Inorganic - chemistry
electromagnetic fields
Ionic Liquids
Magnetics
microwave chemistry
Microwaves
silicon carbide
Silicon Compounds - chemistry
Temperature
thermochemistry
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Zusammenfassung:Running oil‐bath chemistry in a microwave! Using reaction vials made out of strongly microwave‐absorbing silicon carbide (SiC) in a microwave reactor simulates experiments conducted in an autoclave with conductive heating because of the efficient shielding of the electromagnetic field by the SiC vial. This technology makes it possible to study the significance of microwave effects.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200904185