A supramolecular Cu(II) metallocyclophane probe for guanosine 5'-monophosphate

We demonstrate Cu(2+) ion induced formation of a novel water soluble metallocyclophane [.CuCl(2)](2), which uniquely recognizes guanosine 5'-monophosphate through changes in emission intensity utilizing synergistic effects of electrostatic, coordinative and pi-stacking interactions inside the c...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2009-01 (42), p.6352-6354
Hauptverfasser:	Nair, Akhil K, Neelakandan, Prakash P, Ramaiah, Danaboyina
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Sprache:	eng
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creator	Nair, Akhil K Neelakandan, Prakash P Ramaiah, Danaboyina
description	We demonstrate Cu(2+) ion induced formation of a novel water soluble metallocyclophane [.CuCl(2)](2), which uniquely recognizes guanosine 5'-monophosphate through changes in emission intensity utilizing synergistic effects of electrostatic, coordinative and pi-stacking interactions inside the cavity.
doi_str_mv	10.1039/b911855a
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title	A supramolecular Cu(II) metallocyclophane probe for guanosine 5'-monophosphate
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