A supramolecular Cu(II) metallocyclophane probe for guanosine 5'-monophosphate

A supramolecular Cu(II) metallocyclophane probe for guanosine 5'-monophosphate

We demonstrate Cu(2+) ion induced formation of a novel water soluble metallocyclophane [.CuCl(2)](2), which uniquely recognizes guanosine 5'-monophosphate through changes in emission intensity utilizing synergistic effects of electrostatic, coordinative and pi-stacking interactions inside the c...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (42), p.6352-6354
Hauptverfasser: Nair, Akhil K, Neelakandan, Prakash P, Ramaiah, Danaboyina
Format: Artikel
Sprache:eng
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Zusammenfassung:We demonstrate Cu(2+) ion induced formation of a novel water soluble metallocyclophane [.CuCl(2)](2), which uniquely recognizes guanosine 5'-monophosphate through changes in emission intensity utilizing synergistic effects of electrostatic, coordinative and pi-stacking interactions inside the cavity.
ISSN:1359-7345
1364-548X
DOI:10.1039/b911855a