From the Selective Cleavage of the Si-O-Si Bond in Disiloxanes to Zwitterionic, Water-Stable Zinc Silanolates

From the Selective Cleavage of the Si-O-Si Bond in Disiloxanes to Zwitterionic, Water-Stable Zinc Silanolates

Zinc salts do SiO's: Organosilicon chemistry is crucially determined by the high stability and chemical resistance of the Si‐O‐Si bond. The formation and structural existence of water‐stable metallasilanolates demonstrate both the possibility to cleave the Si‐O‐Si bond with simple zinc compoun...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (43), p.8074-8077
Hauptverfasser: Däschlein, Christian, Bauer, Jonathan O, Strohmann, Carsten
Format: Artikel
Sprache:eng
Schlagworte:
metal complexes
metallasilanolates
silicon
zinc
zwitterions
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Zinc salts do SiO's: Organosilicon chemistry is crucially determined by the high stability and chemical resistance of the Si‐O‐Si bond. The formation and structural existence of water‐stable metallasilanolates demonstrate both the possibility to cleave the Si‐O‐Si bond with simple zinc compounds under mild conditions as well as the existence of such molecular metallasilanolates in the presence of water.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200902318