Tunable Aryl Alkyl Ionic Liquids (TAAILs): The Next Generation of Ionic Liquids

Tunable Aryl Alkyl Ionic Liquids (TAAILs): The Next Generation of Ionic Liquids

The combination of aromatic and aliphatic substituents at the imidazolium ring leads to a new generation of imidazolium‐based ionic liquids (TAAILs: tunable aryl alkyl ionic liquids; see charge distribution of the methoxyphenyl methyl derivative). Electronic interaction between the aromatic substitu...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (42), p.7908-7910
Hauptverfasser: Ahrens, Sebastian, Peritz, Anke, Strassner, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
imidazolium salts
ionic liquids
substituent effects
TAAILs
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Zusammenfassung:The combination of aromatic and aliphatic substituents at the imidazolium ring leads to a new generation of imidazolium‐based ionic liquids (TAAILs: tunable aryl alkyl ionic liquids; see charge distribution of the methoxyphenyl methyl derivative). Electronic interaction between the aromatic substituent and the imidazolium core allows the properties of these species to be tuned more precisely than is possible for currently available ionic liquids.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200903399