Alkynylboronic Esters as Efficient Dienophiles in Cobalt-Catalyzed Diels-Alder Reactions

Alkynylboronic Esters as Efficient Dienophiles in Cobalt-Catalyzed Diels-Alder Reactions

Versatile building blocks with a dihydroaromatic vinylic boron substructure can be generated efficiently by cobalt‐catalyzed Diels–Alder reactions and used in Suzuki coupling reactions for the synthesis of functionalized polycyclic compounds (see scheme).

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2003-06, Vol.42 (24), p.2795-2797
Hauptverfasser: Hilt, Gerhard, Smolko, Konstantin I.
Format: Artikel
Sprache:eng
Schlagworte:
alkynes
boron compounds
Diels-Alder reactions
dihydroaromatic compounds
Suzuki reaction
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Versatile building blocks with a dihydroaromatic vinylic boron substructure can be generated efficiently by cobalt‐catalyzed Diels–Alder reactions and used in Suzuki coupling reactions for the synthesis of functionalized polycyclic compounds (see scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351404