Titanium-Promoted Dinitrogen Cleavage, Partial Hydrogenation, and Silylation

Titanium-Promoted Dinitrogen Cleavage, Partial Hydrogenation, and Silylation

Breaking up: Reduction of a trivalent titanium complex afforded NN cleavage with formation of TiIV nitride complexes (see structure), which can be converted into silylated derivatives.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (40), p.7415-7419
Hauptverfasser: Nikiforov, Grigory B, Vidyaratne, Indu, Gambarotta, Sandro, Korobkov, Ilia
Format: Artikel
Sprache:eng
Schlagworte:
dinitrogen cleavage
hydrogenation
nitrides
reduction
titanium
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Beschreibung
Zusammenfassung:Breaking up: Reduction of a trivalent titanium complex afforded NN cleavage with formation of TiIV nitride complexes (see structure), which can be converted into silylated derivatives.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200903648