Palladium-Catalyzed Dehydrogenative Coupling of Furans with Styrenes

Palladium-Catalyzed Dehydrogenative Coupling of Furans with Styrenes

Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products in medium to good yields. The reaction is highly regio- and stereoselective, giving trans-olefins predominantly.

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Veröffentlicht in:Organic letters 2009-09, Vol.11 (18), p.4096-4099
Hauptverfasser: Aouf, Chahinez, Thiery, Emilie, Le Bras, Jean, Muzart, Jacques
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemical synthesis
Catalysis
Furans - chemistry
Oxidation-Reduction
Oxygen - chemistry
Palladium - chemistry
Stereoisomerism
Styrenes - chemistry
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Beschreibung
Zusammenfassung:Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products in medium to good yields. The reaction is highly regio- and stereoselective, giving trans-olefins predominantly.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol901570p