Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

A chemo-, regio-, and stereoselective iron-catalyzed 1,4-hydroboration of dienes that affords γ-disubstituted allylboranes has been developed. 1,4-Hydroboration of 2-substituted dienes forms allylborane products with (E)-trisubstituted double bonds exclusively.

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Veröffentlicht in:Journal of the American Chemical Society 2009-09, Vol.131 (36), p.12915-12917
Hauptverfasser: Wu, Jessica Y, Moreau, Benoît, Ritter, Tobias
Format: Artikel
Sprache:eng
Schlagworte:
Alkadienes - chemistry
Boron Compounds - chemistry
Catalysis
Iron - chemistry
Molecular Structure
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Zusammenfassung:A chemo-, regio-, and stereoselective iron-catalyzed 1,4-hydroboration of dienes that affords γ-disubstituted allylboranes has been developed. 1,4-Hydroboration of 2-substituted dienes forms allylborane products with (E)-trisubstituted double bonds exclusively.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja9048493