A Superior Precursor for Palladium(0)-Based Cross-Coupling and Other Catalytic Reactions

The easily synthesized, easily handled compound Pd(η3-1-PhC3H4)(η5-C5H5) (II) reacts readily with mono- and bidentate tertiary phosphines to produce the corresponding bis-phosphine palladium(0) complexes in good yields; II is thus an excellent precursor, perhaps the most efficacious and reliable ava...

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Veröffentlicht in:	Journal of organic chemistry 2009-09, Vol.74 (17), p.6674-6680
Hauptverfasser:	Norton, Danielle M, Mitchell, Emily A, Botros, Nerine R, Jessop, Philip G, Baird, Michael C
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Organic chemistry Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Beschreibung
Zusammenfassung:	The easily synthesized, easily handled compound Pd(η3-1-PhC3H4)(η5-C5H5) (II) reacts readily with mono- and bidentate tertiary phosphines to produce the corresponding bis-phosphine palladium(0) complexes in good yields; II is thus an excellent precursor, perhaps the most efficacious and reliable available, for the synthesis of palladium(0) cross-coupling catalysts.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo901121e