Synergic anion and cation coordination using the tripodal aluminate anion [MeAl(2-py)(3)](-) (py = 2-pyridyl)

Synergic anion and cation coordination using the tripodal aluminate anion [MeAl(2-py)(3)](-) (py = 2-pyridyl)

The coordination of AlCl(3) by the complex [{MeAl(2-py)(3)}Li.thf] () gives the unusual product [{MeAl(2-py)(3)}(2)Al](+)[{MeAl(2-py)(3)}Li](2)(mu-Cl)(-) (), in which the [MeAl(2-py)(3)](-) aluminate anion of acts cooperatively in the coordination of an Al(3+) cation and Cl(-) anion.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (34), p.6709-6711
Hauptverfasser: Bullock, Thomas H, Chan, Wesley T K, Wright, Dominic S
Format: Artikel
Sprache:eng
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Zusammenfassung:The coordination of AlCl(3) by the complex [{MeAl(2-py)(3)}Li.thf] () gives the unusual product [{MeAl(2-py)(3)}(2)Al](+)[{MeAl(2-py)(3)}Li](2)(mu-Cl)(-) (), in which the [MeAl(2-py)(3)](-) aluminate anion of acts cooperatively in the coordination of an Al(3+) cation and Cl(-) anion.
ISSN:1477-9226
1477-9234
DOI:10.1039/b909933f