Polyoxometalate-supported Pd nanoparticles as efficient catalysts for the direct synthesis of hydrogen peroxide in the absence of acid or halide promoters

A Keggin-type polyoxometalate (Cs(1.5)H(1.5)PW(12)O(40))-supported Pd catalyst is efficient for the direct synthesis of H(2)O(2) from H(2) and O(2) in the absence of any acid or halide additives under atmospheric pressure.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2009-01 (34), p.5174-5176
Hauptverfasser:	Sun, Miao, Zhang, Jizhe, Zhang, Qinghong, Wang, Ye, Wan, Huilin
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Hydrogen Peroxide - chemical synthesis Hydrogen Peroxide - chemistry Metal Nanoparticles - chemistry Organometallic Compounds - chemistry Palladium - chemistry Tungsten Compounds - chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A Keggin-type polyoxometalate (Cs(1.5)H(1.5)PW(12)O(40))-supported Pd catalyst is efficient for the direct synthesis of H(2)O(2) from H(2) and O(2) in the absence of any acid or halide additives under atmospheric pressure.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b910317a