Unprecedented formation of an N-benzamidobisthiourea derivative and its role in the formation of a new CT state specific towards fluoride ion

Unprecedented formation of an N-benzamidobisthiourea derivative and its role in the formation of a new CT state specific towards fluoride ion

A novel N-benzamidobisthiourea derivative (1) was synthesized. Tuning of its emission from the locally excited (LE) state to the charge transfer (CT) state was observed specifically for fluoride ion.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (19), p.3268-3270
Hauptverfasser: Koteeswari, Ranganathan, Ashokkumar, Pichandi, Ramakrishnan, Vayalakkavoor T, Malar, E J Padma, Ramamurthy, Perumal
Format: Artikel
Sprache:eng
Schlagworte:
Computer Simulation
Fluorides - chemistry
Ions - chemistry
Models, Chemical
Molecular Structure
Phase Transition
Quantum Theory
Thiourea - analogs & derivatives
Thiourea - chemical synthesis
Thiourea - chemistry
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Zusammenfassung:A novel N-benzamidobisthiourea derivative (1) was synthesized. Tuning of its emission from the locally excited (LE) state to the charge transfer (CT) state was observed specifically for fluoride ion.
ISSN:1359-7345
1364-548X
DOI:10.1039/b926320a