Hierarchical Self-Assembly of a Chiral Metal-Organic Framework Displaying Pronounced Porosity
Into the void: A large, cavity‐containing trinuclear triangle with accessible binding sites has been synthesized, structurally characterized, and incorporated into a chiral metal–organic framework (see picture). The resulting 3D framework, with a trifunctional amine bridging group, has a void volume...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-02, Vol.49 (6), p.1075-1078 |
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| container_end_page | 1078 |
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| container_issue | 6 |
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| container_title | Angewandte Chemie (International ed.) |
| container_volume | 49 |
| creator | Clegg, Jack K Iremonger, Simon S Hayter, Michael J Southon, Peter D Macquart, René B Duriska, Martin B Jensen, Paul Turner, Peter Jolliffe, Katrina A Kepert, Cameron J Meehan, George V Lindoy, Leonard F |
| description | Into the void: A large, cavity‐containing trinuclear triangle with accessible binding sites has been synthesized, structurally characterized, and incorporated into a chiral metal–organic framework (see picture). The resulting 3D framework, with a trifunctional amine bridging group, has a void volume of 56 % that is accessible to solvent and adsorbs a variety of gases to various degrees. |
| doi_str_mv | 10.1002/anie.200905497 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2010-02, Vol.49 (6), p.1075-1078 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | adsorption coordination modes Metals - chemistry Models, Molecular Molecular Structure Organic Chemicals - chemistry Porosity self-assembly Stereoisomerism supramolecular chemistry |
| title | Hierarchical Self-Assembly of a Chiral Metal-Organic Framework Displaying Pronounced Porosity |
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