Hierarchical Self-Assembly of a Chiral Metal-Organic Framework Displaying Pronounced Porosity

Hierarchical Self-Assembly of a Chiral Metal-Organic Framework Displaying Pronounced Porosity

Into the void: A large, cavity‐containing trinuclear triangle with accessible binding sites has been synthesized, structurally characterized, and incorporated into a chiral metal–organic framework (see picture). The resulting 3D framework, with a trifunctional amine bridging group, has a void volume...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2010-02, Vol.49 (6), p.1075-1078
Hauptverfasser: Clegg, Jack K, Iremonger, Simon S, Hayter, Michael J, Southon, Peter D, Macquart, René B, Duriska, Martin B, Jensen, Paul, Turner, Peter, Jolliffe, Katrina A, Kepert, Cameron J, Meehan, George V, Lindoy, Leonard F
Format: Artikel
Sprache:eng
Schlagworte:
adsorption
coordination modes
Metals - chemistry
Models, Molecular
Molecular Structure
Organic Chemicals - chemistry
Porosity
self-assembly
Stereoisomerism
supramolecular chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Into the void: A large, cavity‐containing trinuclear triangle with accessible binding sites has been synthesized, structurally characterized, and incorporated into a chiral metal–organic framework (see picture). The resulting 3D framework, with a trifunctional amine bridging group, has a void volume of 56 % that is accessible to solvent and adsorbs a variety of gases to various degrees.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905497