A selective electrochemical method of glycosylation of 3beta-hydroxy-Delta 5-steroids
A new electrochemical glycosylation method is presented. According to the method cholesterol and other 3beta-hydroxy-Delta(5)-steroids can be selectively transformed to glycosides using non-activated sugars. The method is also useful for the synthesis of glycoconjugates with sugar linked to a steroi...
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| Veröffentlicht in: | Carbohydrate research 2010-05, Vol.345 (8), p.1051-1055 |
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| container_issue | 8 |
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| container_title | Carbohydrate research |
| container_volume | 345 |
| creator | Morzycki, Jacek W Łotowski, Zenon Siergiejczyk, Leszek Wałejko, Piotr Witkowski, Stanisław Kowalski, Jan Płoszyńska, Jolanta Sobkowiak, Andrzej |
| description | A new electrochemical glycosylation method is presented. According to the method cholesterol and other 3beta-hydroxy-Delta(5)-steroids can be selectively transformed to glycosides using non-activated sugars. The method is also useful for the synthesis of glycoconjugates with sugar linked to a steroid moiety by an ether bond. |
| doi_str_mv | 10.1016/j.carres.2010.03.018 |
| format | Article |
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| fulltext | fulltext |
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| ispartof | Carbohydrate research, 2010-05, Vol.345 (8), p.1051-1055 |
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| language | eng |
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| source | MEDLINE; Elsevier ScienceDirect Journals Complete |
| subjects | Electrochemistry - methods Glycosides - chemical synthesis Glycosides - chemistry Glycosylation Molecular Structure Steroids - chemistry |
| title | A selective electrochemical method of glycosylation of 3beta-hydroxy-Delta 5-steroids |
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