Symmetric Six-Fold Arrays of Photo- and Electrochromic Dithienylethene Switches

The direct synthesis of six-fold symmetric hexaphenylbenzenes with multiple photochromic dithienylethene units via a cobalt-catalyzed cyclotrimerization is reported. This approach allows for six photochromic units to be held in proximity with a well-defined spatial separation without affecting the p...

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Veröffentlicht in:Organic letters 2010-05, Vol.12 (9), p.2132-2135
Hauptverfasser: Areephong, Jetsuda, Logtenberg, Hella, Browne, Wesley R., Feringa, Ben L.
Format: Artikel
Sprache:eng
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Zusammenfassung:The direct synthesis of six-fold symmetric hexaphenylbenzenes with multiple photochromic dithienylethene units via a cobalt-catalyzed cyclotrimerization is reported. This approach allows for six photochromic units to be held in proximity with a well-defined spatial separation without affecting the photochromic properties of each unit.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol1006295