Palladium-catalyzed dehydrogenative direct arylations of 1,2,3-triazoles

Palladium-catalyzed intramolecular dehydrogenative direct arylations of 1,2,3-triazoles were accomplished under ambient pressure of air, which set the stage for a modular synthesis of annulated phenanthrenes through a reaction sequence comprising two distinct catalytic C-H bond functionalization rea...

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Veröffentlicht in:Organic letters 2010-05, Vol.12 (9), p.2056-2059
Hauptverfasser: Ackermann, Lutz, Jeyachandran, Rajkumar, Potukuchi, Harish K, Novák, Petr, Büttner, Lea
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Sprache:eng
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Zusammenfassung:Palladium-catalyzed intramolecular dehydrogenative direct arylations of 1,2,3-triazoles were accomplished under ambient pressure of air, which set the stage for a modular synthesis of annulated phenanthrenes through a reaction sequence comprising two distinct catalytic C-H bond functionalization reactions.
ISSN:1523-7052
DOI:10.1021/ol1005517