Solvent free catalytic C-H functionalisation

Solvent free catalytic C-H functionalisation

Solvent-free reaction conditions facilitate a range of aromatic C-H functionalisations that traditionally require acidic or disfavoured solvents. These reactions include selective ortho- and meta-arylation of aryl carbamates and anilides and selective halogenation reactions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (18), p.3095-3097
Hauptverfasser: Bedford, Robin B, Mitchell, Charlotte J, Webster, Ruth L
Format: Artikel
Sprache:eng
Schlagworte:
Anilides - chemistry
Carbamates - chemistry
Catalysis
Halogenation
Hydrocarbons, Aromatic - chemistry
Molecular Structure
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Beschreibung
Zusammenfassung:Solvent-free reaction conditions facilitate a range of aromatic C-H functionalisations that traditionally require acidic or disfavoured solvents. These reactions include selective ortho- and meta-arylation of aryl carbamates and anilides and selective halogenation reactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c003074k