The highest-nuclearity manganese/oximate complex: an unusual Mn(II/III)15 cluster with an S = 6 ground state

The synthesis, structure, and magnetochemical characterization of the largest manganese oxime cluster are reported. The Mn(15)/2-pyridinealdoxime compound is mixed-valence (II/III) and possesses an irregular structural motif with a novel Mn/O core. The oximato-bridged cluster exhibits an S = 6 groun...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Inorganic chemistry 2010-05, Vol.49 (9), p.3962-3964
Hauptverfasser:	Alexandropoulos, Dimitris I, Papatriantafyllopoulou, Constantina, Aromí, Guillem, Roubeau, Olivier, Teat, Simon J, Perlepes, Spyros P, Christou, George, Stamatatos, Theocharis C
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Magnetics Manganese - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oximes - chemistry Stereoisomerism
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The synthesis, structure, and magnetochemical characterization of the largest manganese oxime cluster are reported. The Mn(15)/2-pyridinealdoxime compound is mixed-valence (II/III) and possesses an irregular structural motif with a novel Mn/O core. The oximato-bridged cluster exhibits an S = 6 ground state and a negative magnetoanisotropy.
ISSN:	1520-510X
DOI:	10.1021/IC100267y