Transannular Addition of Phenols to 1,1′-Dialkynylferrocenes: Unanticipated Formation of Phenoxy[4]ferrocenophanedienes

The reaction of some 1,1′‐dialkynylferrocenes with a variety of phenols in the presence as well as in the absence of [Mo(CO)6] yields good to high yields of phenoxy[4]ferrocenophanedienes. Similar reactivity was observed with a thiophenol and with acetic acid. Reaction under basic reaction condition...

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Veröffentlicht in:	Chemistry : a European journal 2010-02, Vol.16 (6), p.1859-1870
Hauptverfasser:	Ma, Jingxiang, Kühn, Björn, Hackl, Thomas, Butenschön, Holger
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetic acid alkynes Carbon Chemistry Formations Mass spectra Mass spectroscopy metallocenes Phenols regioselectivity Spectra Thiophenol transannular addition
Online-Zugang:	Volltext
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