A rutile-type porous zinc(II)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis

A rutile-type porous zinc(II)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis

The layered-solvothermal synthesis of zinc acetate dihydrate with 5-phosphonobenzene-1,3-dicarboxylic acid yields a three-dimensional rutile-type porous metal-organic framework, which is an anionic open-framework containing local proton transfer with hydrated protons and showing excellent size-selec...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (7), p.1100-1102
Hauptverfasser: Liao, Teng-Biao, Ling, Yun, Chen, Zhen-Xia, Zhou, Ya-Ming, Weng, Lin-Hong
Format: Artikel
Sprache:eng
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Zusammenfassung:The layered-solvothermal synthesis of zinc acetate dihydrate with 5-phosphonobenzene-1,3-dicarboxylic acid yields a three-dimensional rutile-type porous metal-organic framework, which is an anionic open-framework containing local proton transfer with hydrated protons and showing excellent size-selective properties.
ISSN:1359-7345
1364-548X
DOI:10.1039/b917987a