Hydrolysis of 2-phenylazophenyltellurium trihalides: isolation of an unprecedented homometallic, discrete heptanuclear organotellurium oxide cluster

Hydrolysis of 2-phenylazophenyltellurium trihalides: isolation of an unprecedented homometallic, discrete heptanuclear organotellurium oxide cluster

Alkaline hydrolysis of RTeBr(3) (R = 2-phenylazophenyl) gave intramolecularly stabilized homometallic, heptanuclear organotellurium oxide cluster R(6)Te(7)O(11) (4) in good yield.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (7), p.1130-1132
Hauptverfasser: Srivastava, Kriti, Sharma, Sagar, Singh, Harkesh B, Singh, Udai P, Butcher, Ray J
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Hydrolysis
Oxides
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Zusammenfassung:Alkaline hydrolysis of RTeBr(3) (R = 2-phenylazophenyl) gave intramolecularly stabilized homometallic, heptanuclear organotellurium oxide cluster R(6)Te(7)O(11) (4) in good yield.
ISSN:1359-7345
1364-548X
DOI:10.1039/b921785a