Time-Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal-Organic Frameworks

Time-Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal-Organic Frameworks

Inside story: In situ diffraction observations of the crystallization of metal–organic frameworks (MOFs) constructed from transition‐metal ions and carboxylate ligands reveal that while some show classical nucleation‐growth kinetics, others are formed via metastable transient phases (see picture)....

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-01, Vol.49 (4), p.763-766
Hauptverfasser: Millange, Franck, Medina, Manuela I, Guillou, Nathalie, Férey, Gérard, Golden, Kathryn M, Walton, Richard I
Format: Artikel
Sprache:eng
Schlagworte:
crystal growth
metal-organic frameworks
structure elucidation
X-ray diffraction
zeolite analogues
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Beschreibung
Zusammenfassung:Inside story: In situ diffraction observations of the crystallization of metal–organic frameworks (MOFs) constructed from transition‐metal ions and carboxylate ligands reveal that while some show classical nucleation‐growth kinetics, others are formed via metastable transient phases (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905627