Synthesis and structural diversity of oligosilanylzinc compounds

Reactions of potassium oligosilanyls with ZnCl(2) lead to the formation of oligosilanylzinc compounds with zinc's coordination sphere expanded by ligation of TMEDA, an additional oligosilanyl group, or a chloride ion.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (6), p.1598-1603
Hauptverfasser: Gaderbauer, Walter, Balatoni, Istvan, Wagner, Harald, Baumgartner, Judith, Marschner, Christoph
Format: Artikel
Sprache:eng
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Zusammenfassung:Reactions of potassium oligosilanyls with ZnCl(2) lead to the formation of oligosilanylzinc compounds with zinc's coordination sphere expanded by ligation of TMEDA, an additional oligosilanyl group, or a chloride ion.
ISSN:1477-9226
1477-9234
DOI:10.1039/b910463a