Conversion of Oximes to Carbonyl Compounds with 2-Nitro-4,5-dichloropyridazin-3(2H)-one

Conversion of Oximes to Carbonyl Compounds with 2-Nitro-4,5-dichloropyridazin-3(2H)-one

Conversion of oximes to the carbonyl compounds has been demonstrated with use of 2-nitro-4,5-dichloropyridazin-3(2H)-one (2) under microwave irradiated conditions. Fourteen aliphatic and aromatic oximes converted to their corresponding aldehydes and ketones in good to excellent yields. It is notewor...

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Veröffentlicht in:Journal of organic chemistry 2010-01, Vol.75 (2), p.484-486
Hauptverfasser: Kim, Bo Ram, Lee, Hyung-Geun, Kim, Eun Jung, Lee, Sang-Gyeong, Yoon, Yong-Jin
Format: Artikel
Sprache:eng
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Zusammenfassung:Conversion of oximes to the carbonyl compounds has been demonstrated with use of 2-nitro-4,5-dichloropyridazin-3(2H)-one (2) under microwave irradiated conditions. Fourteen aliphatic and aromatic oximes converted to their corresponding aldehydes and ketones in good to excellent yields. It is noteworthy that the reaction is conducted under neutral, mild, and eco-friendly condition.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo902356e