Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform

Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform

A cobalt(ii) complex supported by the new tetradentate polypyridyl ligand PY4 is an electrocatalyst for the reduction of protons to hydrogen and can operate in 50% aqueous media.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (6), p.958-960
Hauptverfasser: Bigi, Julian P, Hanna, Tamara E, Harman, W Hill, Chang, Alicia, Chang, Christopher J
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Cobalt - chemistry
Hydrogen - chemistry
Molecular Conformation
Protons
Pyridines - chemistry
Water - chemistry
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Beschreibung
Zusammenfassung:A cobalt(ii) complex supported by the new tetradentate polypyridyl ligand PY4 is an electrocatalyst for the reduction of protons to hydrogen and can operate in 50% aqueous media.
ISSN:1359-7345
1364-548X
DOI:10.1039/b915846d