A flow cell optosensor for lead based on immobilized gallocynin in chitosan membrane
Gallocynin immobilized in chitosan membrane has been studied as a sensor element of an optical sensor for lead using a flowing system. By using this set up, lead in solution has been determined in the concentration range from 1.0×10 −1 to 1.0×10 3 ppm with a detection limit of 0.075 ppm. The standar...
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Veröffentlicht in: | Talanta (Oxford) 2002-09, Vol.58 (3), p.459-466 |
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description | Gallocynin immobilized in chitosan membrane has been studied as a sensor element of an optical sensor for lead using a flowing system. By using this set up, lead in solution has been determined in the concentration range from 1.0×10
−1 to 1.0×10
3 ppm with a detection limit of 0.075 ppm. The standard deviation of the method for the repeatability of lead detection at a concentration of 100 ppm was found to be 2.10%. The response of the sensor was reproducible and can be regenerated by using acidified saturated KNO
3 solution. Interference from foreign ions was also studied at 1:1 mole ratio of Pb(II):foreign ions. |
doi_str_mv | 10.1016/S0039-9140(02)00308-9 |
format | Article |
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−1 to 1.0×10
3 ppm with a detection limit of 0.075 ppm. The standard deviation of the method for the repeatability of lead detection at a concentration of 100 ppm was found to be 2.10%. The response of the sensor was reproducible and can be regenerated by using acidified saturated KNO
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−1 to 1.0×10
3 ppm with a detection limit of 0.075 ppm. The standard deviation of the method for the repeatability of lead detection at a concentration of 100 ppm was found to be 2.10%. The response of the sensor was reproducible and can be regenerated by using acidified saturated KNO
3 solution. Interference from foreign ions was also studied at 1:1 mole ratio of Pb(II):foreign ions.</description><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Chitosan membrane</subject><subject>Exact sciences and technology</subject><subject>Flow injection analysis (FIA)</subject><subject>General, instrumentation</subject><subject>Optical fibre</subject><subject>Pb(II) sensor</subject><issn>0039-9140</issn><issn>1873-3573</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNqFkE1PXCEUhompqVPbn6Bh07Rd3HqAOxdYNcb0w8TEhXZNuHBQGu5lhJk29teXcSZ16YKQQ55zOO9DyAmDzwzYcHYDIHSnWQ8fgX9qBahOH5AFU1J0YinFK7L4jxyRN7X-AgAuQLwmR0zpQUnJF-T2nIaU_1CHKdG8WueKc82FhnYSWk9HW9HTPNM4TXmMKf5t5Z1NKbvHObbnmbr72PrsTCecxmJnfEsOg00V3-3vY_Lz29fbix_d1fX3y4vzq84JzdedwiH0Cj0XY5BaeMFVr9GNXmvpUbJBasW4g4GDtJxZ65VDBwGY8jq0nMfkw27uquSHDda1mWLdJmk75E01UgjFtebLRi53pCu51oLBrEqcbHk0DMzWp3nyabayDHDz5NPo1ne6_2EzTuifu_YCG_B-D9jqbAotvov1mRNK97LfDvqy47D5-B2xmOoizg59LOjWxuf4wir_AHAdkes</recordid><startdate>20020912</startdate><enddate>20020912</enddate><creator>Yusof, Nor Azah</creator><creator>Ahmad, Musa</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20020912</creationdate><title>A flow cell optosensor for lead based on immobilized gallocynin in chitosan membrane</title><author>Yusof, Nor Azah ; Ahmad, Musa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-8e6f48ed23bf793d32849ecbd997de71679812c06207a21aad8cec0f018d9f873</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>Chitosan membrane</topic><topic>Exact sciences and technology</topic><topic>Flow injection analysis (FIA)</topic><topic>General, instrumentation</topic><topic>Optical fibre</topic><topic>Pb(II) sensor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yusof, Nor Azah</creatorcontrib><creatorcontrib>Ahmad, Musa</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Talanta (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yusof, Nor Azah</au><au>Ahmad, Musa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A flow cell optosensor for lead based on immobilized gallocynin in chitosan membrane</atitle><jtitle>Talanta (Oxford)</jtitle><addtitle>Talanta</addtitle><date>2002-09-12</date><risdate>2002</risdate><volume>58</volume><issue>3</issue><spage>459</spage><epage>466</epage><pages>459-466</pages><issn>0039-9140</issn><eissn>1873-3573</eissn><coden>TLNTA2</coden><abstract>Gallocynin immobilized in chitosan membrane has been studied as a sensor element of an optical sensor for lead using a flowing system. By using this set up, lead in solution has been determined in the concentration range from 1.0×10
−1 to 1.0×10
3 ppm with a detection limit of 0.075 ppm. The standard deviation of the method for the repeatability of lead detection at a concentration of 100 ppm was found to be 2.10%. The response of the sensor was reproducible and can be regenerated by using acidified saturated KNO
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source | Elsevier ScienceDirect Journals |
subjects | Analytical chemistry Chemistry Chitosan membrane Exact sciences and technology Flow injection analysis (FIA) General, instrumentation Optical fibre Pb(II) sensor |
title | A flow cell optosensor for lead based on immobilized gallocynin in chitosan membrane |
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