Flexible metal-organic supramolecular isomers for gas separation

Flexible metal-organic supramolecular isomers for gas separation

Three interpenetrated metal-organic supramolecular isomers were synthesised using a flexible tetrahedral organic linker and Zn(2) clusters that sorb CO(2) preferably over N(2), H(2) and methane at room temperature.

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Veröffentlicht in:Chemical Communications, 46(4):538-540 46(4):538-540, 2010-01, Vol.46 (4), p.538-540
Hauptverfasser: Kishan, Motkuri Radha, Tian, Jian, Thallapally, Praveen K, Fernandez, Carlos A, Dalgarno, Scott J, Warren, John E, McGrail, B Peter, Atwood, Jerry L
Format: Artikel
Sprache:eng
Schlagworte:
ADSORPTION
CARBON-DIOXIDE
Clusters
CO2
COORDINATION POLYMER
FRAMEWORKS
Gas separation
gas sepration
GASES
HIGH-CAPACITY
HYDROGEN STORAGE
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
ISOMERS
Metal-organic frameworks
Methane
METHANE STORAGE
MOLECULES
PLATINUM SULFIDES
SEPARATION PROCESSES
SITES
supramolecular isomers
SYNTHESIS
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Beschreibung
Zusammenfassung:Three interpenetrated metal-organic supramolecular isomers were synthesised using a flexible tetrahedral organic linker and Zn(2) clusters that sorb CO(2) preferably over N(2), H(2) and methane at room temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/b913910a